{"id":9576,"date":"2018-05-31T14:08:38","date_gmt":"2018-05-31T19:08:38","guid":{"rendered":"http:\/\/blog.wika.com\/us\/\/?p=9576"},"modified":"2023-08-25T02:26:31","modified_gmt":"2023-08-25T07:26:31","slug":"grain-growth-type-k-thermocouples","status":"publish","type":"post","link":"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/","title":{"rendered":"Grain Growth in Type K Thermocouples: Some Causes and Solutions"},"content":{"rendered":"<p><strong>Extremely high temperatures over time lead to grain growth in type K thermocouples, which can cause metal separation and thermocouple failure. Fortunately, good solutions exist for minimizing the effect of grain growth.<\/strong><\/p>\n<p>Grain growth is a common cause of failure in type K <a href=\"https:\/\/www.wika.com\/en-us\/thermocouples.WIKA\" rel=\"external\" target=\"_blank\">thermocouples<\/a>. In applications such as tubeskin temperature measurement in fired process furnaces, the temperature measurement device is exposed to process gas and radiant energy, creating temperatures that are much higher than the tubeskin temperature measuring junction. Elevated temperature over time is the overriding factor in grain growth that ultimately damages the thermocouple.<\/p>\n<h2>The Causes and Effects of Grain Growth<\/h2>\n\n      <div class=\"wp-caption alignright\" style=\"max-width:396px;\"><img decoding=\"async\" src=\"https:\/\/blog.wika.com\/us\/\/files\/2018\/05\/wed-mar-21-11-08-41-388x291.jpg\" \/><p class=\"wp-caption-text\">Example of a metal&#8217;s crystal structure<\/p><\/div>\n    \n<p>Grain growth is a condition where a material\u2019s crystallites, or grains, become larger. In thermocouples, it is a failure mode that has to do with a metal\u2019s grain structure, different coefficients of expansion, and an application\u2019s high temperatures \u2013 above 1,200<span>\u00b0<\/span>F (649\u00b0C) for type K.<\/p>\n<p><span>A sheathed thermocouple contains three different types of metals: one in the positive conductor, another in the negative conductor, and a third type in the sheath. The sheath is usually made of stainless steel or another alloy, while each <\/span><a href=\"https:\/\/www.wika.com\/en-us\/thermocouples.WIKA\" rel=\"external\" target=\"_blank\"><span>type of thermocouple<\/span><\/a><span>has a specific pairing of metal conductors. Type K, the most commonly used thermocouple, has a NiCr (Chromel\u00ae) positive leg and a NiAl (Alumel\u00ae) negative leg.<\/span><\/p>\n<p><span>Each metal has a different coefficient of expansion \u2013 stainless steel has the largest, and the negative leg has the smallest. As a result, every time a type K thermocouple is exposed to high temperatures, the negative conductor leg undergoes stress. The crystal structure of NiAl goes from having many small grains (worked or manufactured state) to a few large grains (relaxed state). The large crystal structure has less mechanical \u201croughness\u201d and fewer \u201cledges,\u201d causing the negative conductor to actually separate when stressed by the differential expansion. <\/span>Small conductors are also more susceptible to grain growth than large ones.<\/p>\n<p>Grain growth and failure in type K thermocouples has been well established. In one test, type K thermocouples sheathed in 310 stainless steel with a \u00bc\u201doutside diameter (OD) were subjected constantly to temperatures between 2,000<span>\u00b0<\/span>F and 2,100<span>\u00b0<\/span>F (1,093\u00b0C and 1,149\u00b0C). All samples showed extensive grain growth of two to five grains in cross-sections of the Alumel wire over time, though not all of them failed. The failure rates over time:<\/p>\n<ul>\n<li>10% in three months<\/li>\n<li>60% in six months<\/li>\n<li>72% in eleven months<\/li>\n<\/ul>\n<h2>How to Reduce Grain Growth and Minimize Its Impact<\/h2>\n<p>There are three main ways to reduce grain growth in type K thermocouples.<\/p>\n<ol>\n<li><strong> Sheath materials<\/strong>: One way is to choose a sheath material with a coefficient that closely matches those of the conductors. Conventional sheaths are often made of 310 stainless steel. The large difference between the sheath\u2019s and Alumel\u2019s coefficients of expansion led to the high rates of thermocouple failure in the test mentioned above. If conductor and sheath expansion coefficients are the same, grain growth is dramatically reduced or even completely eliminated.<\/li>\n<\/ol>\n<p><span>Inconel\u00ae 600 has a coefficient of expansion that is closer to those of the conductor wires. <\/span>This alloy <span>works well at high temperatures but only in environments without sulfur or another reducing agent, which can cause <a href=\"http:\/\/blog.wika.com\/us\/\/products\/temperature-products\/green-rot-affects-type-k-thermocouples\/\">chromium oxidation, or \u201cgreen rot.\u201d<\/a><\/span><\/p>\n<p><span>I600 was the material of choice for reducing grain growth for many years, until new materials came along. Pyrosil\u00aeD or Incotherm\u00ae Alloy TD \u2013 these are the same product but made by different manufacturers \u2013 confer even better protection against grain growth. This alloy is formulated to contain fewer contaminants than stainless steel and has a coefficient of expansion that almost exactly matches type N thermocouple\u2019s conductor expansion. In fact, for high-temperature furnace applications, it has become standard practice for major refinery companies to use thermocouples sheathed in Pyrosil\/Alloy TD.<\/span><\/p>\n<ol start=\"2\">\n<li><strong><span> Engineered cables: <\/span><\/strong><span>Because <\/span>smaller conductors are more susceptible to grain growth than larger ones, \u201cengineered cables\u201d can combat this condition. WIKA uses non-standard MI (mineral-insulated) cables designed to our specifications. The negative leg is made to be larger, which gives it greater resistance to grain-growth separation.\n<\/li>\n<li><strong> Thermocouple placement: <\/strong>For <span>fired process furnaces, keeping the thermocouple sheath in contact with the furnace tubes and using the tubes as heat sinks are two ways to keep the thermocouple at a much lower temperature than that of the surrounding gas, thereby extending thermocouple lifetimes and decreasing failure rates. <\/span><\/li>\n<\/ol>\n<p><span>As long as type K thermocouples are repeatedly exposed to extremely high temperatures, grain growth is a possibility. But thanks to newer, better metallurgies and engineering, grain growth is no longer the major threat it used to be. <\/span><a href=\"https:\/\/www.wika.com\/en-us\/contact.WIKA\" rel=\"external\" target=\"_blank\"><span>WIKA\u2019s temperature measurement specialists<\/span><\/a><span>understand furnace <\/span><a href=\"https:\/\/www.wika.com\/en-us\/tc59_v.WIKA\" rel=\"external\" target=\"_blank\"><span>tubeskin thermocouples<\/span><\/a><span>and the unique requirements of refineries. Contact them to learn about the <\/span><a href=\"https:\/\/www.wika.com\/en-us\/thermocouples.WIKA\" rel=\"external\" target=\"_blank\"><span>best thermocouple types and assemblies<\/span><\/a><span>for your applications.<\/span><\/p>\n<p>Click here to enter our <a href=\"http:\/\/bit.ly\/2FueOzI\" rel=\"external\" target=\"_blank\">interactive refinery<\/a> to learn more about WIKA product applications.<\/p>\n<figure><img decoding=\"async\" src=\"https:\/\/blog.wika.com\/us\/\/files\/2018\/06\/refinery-roadmap-388x218.jpg\" alt=\"Graphic depicting an overview of a typical refinery\" class=\"alignnone\" \/><\/figure>\n<p>[contact-form-7 id=&#8221;14552&#8243; title=&#8221;Blog Contact Form&#8221;]<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Extremely high temperatures over time lead to grain growth in type K thermocouples, which can cause metal separation and thermocouple failure. Fortunately, good solutions exist for minimizing the effect of grain growth. Grain growth is a common cause of failure in type K thermocouples. In applications such as tubeskin temperature measurement in fired process furnaces, [&hellip;]<\/p>\n","protected":false},"author":190,"featured_media":9559,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[221],"tags":[437,323,765],"class_list":["post-9576","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-temperature-products","tag-temperature-measurement","tag-thermocouple","tag-type-k-thermocouple"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.2 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Ways to Minimize Grain Growth in Type K Thermocouples<\/title>\n<meta name=\"description\" content=\"Extremely high temperatures over time leads to grain growth in type K thermocouples, which can cause conductor breakage and failure in these popular temperature measurement devices. New metallurgies, engineered cables, and better thermocouple placement can minimize grain growth and its negative consequences.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Ways to Minimize Grain Growth in Type K Thermocouples\" \/>\n<meta property=\"og:description\" content=\"Extremely high temperatures over time leads to grain growth in type K thermocouples, which can cause conductor breakage and failure in these popular temperature measurement devices. New metallurgies, engineered cables, and better thermocouple placement can minimize grain growth and its negative consequences.\" \/>\n<meta property=\"og:url\" content=\"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/\" \/>\n<meta property=\"og:site_name\" content=\"WIKA blog\" \/>\n<meta property=\"og:image\" content=\"https:\/\/blog.wika.com\/us\/files\/2018\/05\/grain-growth-copyright-shutterstock.jpg\" \/>\n\t<meta property=\"og:image:width\" content=\"4896\" \/>\n\t<meta property=\"og:image:height\" content=\"3264\" \/>\n\t<meta property=\"og:image:type\" content=\"image\/jpeg\" \/>\n<meta name=\"author\" content=\"Robert Torgerson\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Robert Torgerson\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"4 minutes\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/#article\",\"isPartOf\":{\"@id\":\"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/\"},\"author\":{\"name\":\"Robert Torgerson\",\"@id\":\"https:\/\/blog.wika.com\/us\/#\/schema\/person\/1a0b56b9c563f8b638494f482ea9eff2\"},\"headline\":\"Grain Growth in Type K Thermocouples: Some Causes and Solutions\",\"datePublished\":\"2018-05-31T19:08:38+00:00\",\"dateModified\":\"2023-08-25T07:26:31+00:00\",\"mainEntityOfPage\":{\"@id\":\"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/\"},\"wordCount\":824,\"commentCount\":0,\"image\":{\"@id\":\"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/#primaryimage\"},\"thumbnailUrl\":\"https:\/\/blog.wika.com\/us\/files\/2018\/05\/grain-growth-copyright-shutterstock.jpg\",\"keywords\":[\"temperature measurement\",\"Thermocouple\",\"type K thermocouple\"],\"articleSection\":[\"Temperature\"],\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"CommentAction\",\"name\":\"Comment\",\"target\":[\"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/#respond\"]}]},{\"@type\":\"WebPage\",\"@id\":\"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/\",\"url\":\"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/\",\"name\":\"Ways to Minimize Grain Growth in Type K Thermocouples\",\"isPartOf\":{\"@id\":\"https:\/\/blog.wika.com\/us\/#website\"},\"primaryImageOfPage\":{\"@id\":\"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/#primaryimage\"},\"image\":{\"@id\":\"https:\/\/blog.wika.com\/us\/products\/temperature-products\/grain-growth-type-k-thermocouples\/#primaryimage\"},\"thumbnailUrl\":\"https:\/\/blog.wika.com\/us\/files\/2018\/05\/grain-growth-copyright-shutterstock.jpg\",\"datePublished\":\"2018-05-31T19:08:38+00:00\",\"dateModified\":\"2023-08-25T07:26:31+00:00\",\"author\":{\"@id\":\"https:\/\/blog.wika.com\/us\/#\/schema\/person\/1a0b56b9c563f8b638494f482ea9eff2\"},\"description\":\"Extremely high temperatures over time leads to grain growth in type K thermocouples, which can cause conductor breakage and failure in these popular temperature measurement devices. 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